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Technical Paper

Technical Advantages of Urea SCR for Light-Duty and Heavy-Duty Diesel Vehicle Applications

2004-03-08
2004-01-1292
The 2007 emission standards for both light-duty and heavy-duty diesel vehicles remain a challenge. A level of about 90% NOx conversion is required to meet the standards. Technologies that have the most potential to achieve very high NOx conversion at low temperatures of diesel exhaust are lean NOx traps (LNTs) and Selective Catalytic Reduction (SCR) of NOx using aqueous urea, typically known as Urea SCR. The LNT has the advantage of requiring no new infrastructure, and does not pose any new customer compliance issues. However, Urea SCR has high and durable NOx conversion in a wider temperature window, a lower equivalent fuel penalty, and lower system cost. On a technical basis, Urea SCR has the best chance of meeting the 2007 NOx targets. This paper reviews the results of some demonstration programs for both light-and heavy-duty applications.
Technical Paper

System Level Simulation of H2 ICE after Treatment System

2024-04-09
2024-01-2625
Hydrogen Internal Combustion Engines (H2 ICE) are gaining recognition as a nearly emission-free alternative to traditional ICE engines. However, H2 ICE systems face challenges related to thermal management, N2O emissions, and reduced SCR efficiency in high humidity conditions (15% H2O). This study assesses how hydrogen in the exhaust affects after-treatment system components for H2 ICE engines, such as Selective Catalytic Reduction (SCR), Hydrogen Oxidation Catalyst (HOC), and Ammonia Slip Catalyst (ASC). Steady-state experiments with inlet H2 inlet concentrations of 0.25% to 1% and gas stream moisture levels of up to 15% H2O were conducted to characterize the catalyst response to H2 ICE exhaust. The data was used to calibrate and validate system component models, forming the basis for a system simulation.
Technical Paper

SwRI-BMW N.A. Intake Valve Deposit Test - A Statistical Review

1992-10-01
922215
The SwRI/BMW N.A. Intake Valve Deposit Test procedure was the first performance-based test procedure adopted for fuels qualification in the United States. The initial fuel evaluations were begun in January 1988 with six 1985 BMW 318i vehicles. Since that time, the fleet has grown to include over 60 BMW cars, and more than 2000 tests have been performed. This paper gives a statistical summary of approximately 1800 tests performed over a four-year period. Performance data and possible sources of test variation are discussed. Data and analyses offered represent results of tests by all clients. However, data is presented such that no individual test or client is identified.
Technical Paper

Survey of Low Sulfur Diesel Fuels and Aviation Kerosenes from U.S. Military Installations

1995-10-01
952369
In support of the Department of Defense goal to streamline procurements, the Army recently decided to discontinue use of VV-F-800D as the purchase specification for diesel fuel being supplied to continental United States military installations. The Army will instead issue a commercial item description for direct fuel deliveries under the Post-Camp-Station (PCS) contract bulletin program. In parallel, the Defense Fuel Supply Center and the U.S. Army Mobility Technology Center-Belvoir (at Ft. Belvoir, VA) initiated a fuel survey with the primary objective to assess the general quality and lubricity characteristics of low sulfur diesel fuels being supplied to military installations under the PCS system. Under this project, diesel fuel delivery samples were obtained from selected military installations and analyzed according to a predetermined protocol.
Technical Paper

Stress Generation in Large Pouch Cells Under Cycling and Abuse Conditions

2024-04-09
2024-01-2196
Pouch cells are increasingly popular form factors for the construction of energy storage systems in electric vehicles of all classes. Knowledge of the stress generated by these higher capacity pouch cells is critical to properly design battery modules and packs for both normal and abnormal operation. Existing literature predominantly offers data on smaller pouch cells with capacities of less than 10 Ah, leaving a gap in our understanding of the behavior of these larger cells. This experimental study aimed to bridge this knowledge gap by measuring loads and stresses in constrained 65 Ah pouch cells under both cycling and abuse conditions. To capture the desired responses, a load cell was located within a robust fixture to measure cell stress in real time after the application of a preload of approximately 30 kilograms or 294 N, equivalent to a pressure of 0.063 bar, with a fixed displacement.
Technical Paper

Solid Particle Number and Ash Emissions from Heavy-Duty Natural Gas and Diesel w/SCRF Engines

2018-04-03
2018-01-0362
Solid and metallic ash particle number (PN) and particulate matter (PM) mass emission measurements were performed on a heavy-duty (HD) on-highway diesel engine and a compressed natural gas (CNG) engine. Measurements were conducted under transient engine operation that included the FTP, WHTC and RMC. Both engines were calibrated to meet CARB ultra low NOX emission target of 0.02 g/hp-hr, a 90% reduction from current emissions limit. The HD diesel engine final exhaust configuration included a number of aftertreatement sub-systems in addition to a selective catalytic reduction filter (SCRF). The stoichiometric CNG engine final configuration included a closed coupled Three Way Catalyst (ccTWC) and an under floor TWC (ufTWC). The aftertreatment systems for both engines were aged for a full useful life (FUL) of 435,000 miles, prior to emissions testing. PM mass emissions from both engines were comparable and well below the US EPA emissions standard.
Journal Article

Solid Particle Emissions from Vehicle Exhaust during Engine Start-Up

2015-04-14
2015-01-1077
Human exposure to vehicle exhaust during engine start-up can be encountered on a daily basis in parking lots, home garages, and vehicle stop/star traffic environment. This work is the first pilot study to characterize solid particle number and size distribution during engine start-up using various light-duty vehicles with different technology engines. A total of 84 vehicles were tested in this pilot study, consisting of post-2007 diesel engines equipped with high efficiency diesel particulate filters (DPFs) as well as modern gasoline port fuel injected (PFI) and gasoline direct injected (GDI) engines equipped with three-way-catalysts (TWCs). Particle concentration from DPF equipped diesel engines were found to be the lowest, while GDI and 8-cylinder PFI engines had the highest particle emissions.
Technical Paper

Soak Time Effects on Car Emissions and Fuel Economy

1978-02-01
780083
Five light-duty vehicles were used to investigate HC, CO, and NOx emissions and fuel economy sensitivity to changes in the length of soak period preceding the EPA Urban Dynamometer Driving Schedule (UDDS). Emission tests were conducted following soak periods 10 minutes to 36 hours in length. Each of the first 8 minutes of the driving cycle was studied separately to observe vehicle warm-up. Several engine and fuel system temperatures were monitored during soak and run periods and example trends are illustrated. The extent to which emission rates and fuel consumption are affected by soak period length is discussed.
Technical Paper

Snowmobile Engine Emissions and Their Impact

1974-02-01
740735
This paper describes a research program on exhaust emissions from snowmobile engines, including both emissions characterization and estimation of national emissions impact. Tests were conducted on three popular 2-stroke twins and on one rotary (Wankel) engine. Emissions that were measured included total hydrocarbons, (paraffinic) hydrocarbons by NDIR, CO, CO2, NO (by two methods), NOx, O2, aldehydes, light hydrocarbons, particulate, and smoke. Emissions of SOx were estimated on the basis of fuel consumed, and evaporative hydrocarbons were projected to be negligible for actual snowmobile operation. During emissions tests, intake air temperature was controlled to approximately -7°C (20°F), and room air at approximately 24°C (75°F) was used for engine cooling. Based on test results and the best snowmobile population and usage data available, impact of snowmobile emissions on a national scale was computed to be minimal.
Journal Article

Scuderi Split Cycle Research Engine: Overview, Architecture and Operation

2011-04-12
2011-01-0403
The Scuderi engine is a split cycle design that divides the four strokes of a conventional combustion cycle over two paired cylinders, one intake/compression cylinder and one power/exhaust cylinder, connected by a crossover port. This configuration provides potential benefits to the combustion process, as well as presenting some challenges. It also creates the possibility for pneumatic hybridization of the engine. This paper reviews the first Scuderi split cycle research engine, giving an overview of its architecture and operation. It describes how the splitting of gas compression and combustion into two separate cylinders has been simulated and how the results were used to drive the engine architecture together with the design of the main engine systems for air handling, fuel injection, mixing and ignition. A prototype engine was designed, manufactured, and installed in a test cell. The engine was heavily instrumented and initial performance results are presented.
Technical Paper

Scuderi Split Cycle Engine: Air Hybrid Vehicle Powertrain Simulation Study

2012-04-16
2012-01-1013
The Scuderi engine is a split cycle design that divides the four strokes of a conventional combustion cycle over two paired cylinders, one intake/compression cylinder and one power/exhaust cylinder, connected by a crossover port. This configuration provides potential benefits to the combustion process, as well as presenting some challenges; it also creates the possibility for pneumatic hybridization of the engine. This paper presents the methodology and results of a comprehensive study to investigate the benefits of air hybrid operation with the Scuderi Split Cycle (SSC) engine. Four air hybrid operating modes are made possible by the Split Cycle configuration, namely air compressor, air expander, air expander & firing and firing & charging. The predicted operating requirements for each individual operating mode are established. The air and fuel flow of the individual modes are fully mapped throughout the engine operating speed and load range and air tank pressure operating range.
Video

SCR Deactivation Study for OBD Applications

2012-06-18
Selective catalytic reduction (SCR) catalysts will be used to reduce oxides of nitrogen (NOx) emissions from internal combustion engines in a number of applications [1,2,3,4]. Southwest Research Institute® (SwRI)® performed an Internal Research & Development project to study SCR catalyst thermal deactivation. The study included a V/W/TiO2 formulation, a Cu-zeolite formulation and an Fe-zeolite formulation. This work describes NOx timed response to ammonia (NH3) transients as a function of thermal aging time and temperature. It has been proposed that the response time of NOx emissions to NH3 transients, effected by changes in diesel emissions fluid (DEF) injection rate, could be used as an on-board diagnostic (OBD) metric. The objective of this study was to evaluate the feasibility and practicality of this OBD approach.
Technical Paper

SCR Deactivation Study for OBD Applications

2012-04-16
2012-01-1076
Selective catalytic reduction (SCR) catalysts will be used to reduce oxides of nitrogen (NOx) emissions from internal combustion engines in a number of applications. Southwest Research Institute® (SwRI)® performed an Internal Research & Development project to study SCR catalyst thermal deactivation. The study included a V/W/TiO₂ formulation, a Cu-zeolite formulation and an Fe-zeolite formulation. This work describes NOx timed response to ammonia (NH₃) transients as a function of thermal aging time and temperature. It has been proposed that the response time of NOx emissions to NH₃ transients, effected by changes in diesel emissions fluid (DEF) injection rate, could be used as an on-board diagnostic (OBD) metric. The objective of this study was to evaluate the feasibility and practicality of this OBD approach.
Video

SCR Deactivation Kinetics for Model-Based Control and Accelerated Aging Applications

2012-06-18
This paper forms the third of a series and presents results obtained during the testing and development phase of a dedicated range extender engine designed for use in a compact class vehicle. The first paper in this series used real world drive logs to identify usage patterns of such vehicles and a driveline model was used to determine the power output requirements of a range extender engine for this application. The second paper presented the results of a design study. Key attributes for the engine were identified, these being minimum package volume, low weight, low cost, and good NVH. A description of the selection process for identifying the appropriate engine technology to satisfy these attributes was given and the resulting design highlights were described. The paper concluded with a presentation of the resulting specification and design highlights of the engine. This paper will present the resulting engine performance characteristics.
Technical Paper

SCR Deactivation Kinetics for Model-Based Control and Accelerated Aging Applications

2012-04-16
2012-01-1077
Selective Catalytic Reduction (SCR) catalysts are used to reduce NOx emissions from internal combustion engines in a variety of applications. Southwest Research Institute (SwRI) performed an Internal Research & Development project to study SCR catalyst thermal deactivation. The study included a V/W/TiO₂ formulation, a Cu-zeolite formulation and a Fe-zeolite formulation. This work describes NH₃ storage capacity measurement data as a function of aging time and temperature. Addressing one objective of the work, these data can be used in model-based control algorithms to calculate the current NH₃ storage capacity of an SCR catalyst operating in the field, based on time and temperature history. The model-based control then uses the calculated value for effective DEF control and prevention of excessive NH₃ slip. Addressing a second objective of the work, accelerated thermal aging of SCR catalysts may be achieved by elevating temperatures above normal operating temperatures.
Technical Paper

Roadmap for Hybridization of Military Tactical Vehicles: How Can We Get There?

2002-11-18
2002-01-3048
The U.S. Army's National Automotive Center has contracted with Illinois Institute of Technology Research Institute (IITRI), Southwest Research Institute (SwRI), and Advanced Propulsion, LLC, to evaluate the effects on fuel consumption and logistics that would result from hybridizing the powertrains of the Army's tactical wheeled vehicle fleet. This paper will outline the approach taken to perform that evaluation and present a synopsis of results achieved to date.
Technical Paper

Review of the Computer Science and Engineering Solutions for Model Sharing and Model Co-Simulation

2019-03-19
2019-01-1352
The process of developing, parameterizing, validating, and maintaining models occurs within a wide variety of tools, and requires significant time and resources. To maximize model utilization, models are often shared between various toolsets and experts. One common example is sharing aircraft engine models with airframers. The functionality of a given model may be utilized and shared with a secondary model, or multiple models may run collaboratively through co-simulation. There are many technical challenges associated with model sharing and co-simulation. For example, data communication between models and tools must be accurate and reliable, and the model usage must be well-documented and perspicuous for a user. This requires clear communication and understanding between computer scientists and engineers. Most often, models are developed by engineers, whereas the tools used to share the models are developed by computer scientists.
Technical Paper

Reduced Cold-Start Emissions Using Rapid Exhaust Port Oxidation (REPO) in a Spark-Ignition Engine

1997-02-24
970264
An emissions reduction strategy was developed and demonstrated to significantly reduce cold-start hydrocarbon (HC) and CO emissions from a spark ignition (SI), gasoline-fueled engine. This strategy involved cold-starting the engine with an ultra-fuel rich calibration, while metering near-stoichiometric fractions of air directly into the exhaust ports. Using this approach, exhaust constituents spontaneously ignited at the exhaust ports and burned into the exhaust manifold and exhaust pipe leading to the catalytic converter. The resulting exotherm accelerated catalyst heating and significantly decreased light-off time following a cold-start on the FTP-75 with a Ford Escort equipped with a 1.9L engine. Mass emissions measurements acquired during the first 70 seconds of the FTP-75 revealed total-HC and CO reductions of 68 and 50 percent, respectively, when compared to baseline measurements.
Technical Paper

Real-Time Steady-State Oil Consumption Measurement on Commercial SI-Engine

1999-10-25
1999-01-3461
The oil consumption has been measured in real-time for steady-state operating conditions for an approximately 2 L SI-engine. These oil consumption measurements have been obtained for the engine stack (total) as well as for the individual engine cylinders with the current generation of Southwest Research Institute (SwRI) developed SO2 analyzers. The 10 steady-state data presented in this paper is only a small fraction of the 234 steady-state data taken as part of this project. This paper is important since few complete data sets have been published in this area of research and since it illustrates the technical superiority of this analyzing tool for engine development purposes.
Technical Paper

Reactivity and Exhaust Emissions from an EHC-Equipped LPG Conversion Vehicle Operating on Butane/Propane Fuel Blends

1996-10-01
961991
This paper describes experiments conducted to determine Federal Test Procedure (FTP) exhaust emissions, ozone-forming potentials, specific reactivities, and reactivity adjustment factors for several butane/propane alternative fuel blends run on a light-duty EHC-equipped gasoline vehicle converted to operate on liquefied petroleum gas (LPG). Duplicate emission tests were conducted on the light-duty vehicle at each test condition using appropriate EPA FTP test protocol. Hydrocarbon speciation was utilized to determine reactivity-adjusted non-methane organic gas (NMOG) emissions for one test on each fuel.
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